The only way to export .dsn schematics from OrCAD PCB Designer is to open them in the original software or some kind of viewer and print them as PDF using a virtual PDF printer installed. It seems there is no default PDF export function in OrCAD.
Convert OrCAD schematic capture data to Adobe Portable document format.
We found one software available in the database for this conversion.
Microsoft Windows software - convert dsn to pdf on Windows
A modeling suite used to design printed circuit boards
Convert from dsn file format
The table with program actions contains information about what each program is capable of doing with their files. This may be a good pointer for further searches for certain file conversions and help you find the converter you are looking for if our search result is insufficient for you. However, it is far from perfect and may sometimes show results which are not really usable because of the nature of the software handles the files. So a conversion that appears as possible, just because of matched actions, may in fact not be possible.